Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138
A variety of theoretical studies over the past two decades have indicated that gaseous water should be a powerful coolant of warm, dense gas in the interstellar medium. These predictions were motivated by three assumptions: (1) chemical models suggest that above gas temperatures of about 400 K water is produced rapidly and in great abundance; (2) owing to water's large dipole moment, the cooling rate is minimally quenched by collisional de-excitations over a broad range of densities; and (3) water's many transitions allow it to radiate efficiently over a broad range of gas temperatures. Unfortunately, before ISO, the role of water in the ISM went untested due to the difficulty of making such measurements from within the atmosphere. We report the findings of both SWS and LWS observations of gaseous water towards both star forming and circumstellar regions. These observations confirm the above assumptions and demonstrate that water, along with H2 and CO, is a major gas coolant. In particular, observations toward Orion-KL indicate that the post-shock chemical processing into water of all gas-phase oxygen not bound in CO results in a high water abundance, i.e. H2O/H2 on the order of . Similarly, spectra obtained towards the oxygen-rich late-type stars W Hydrae and VYCMa exhibit strong water emission in a large number of lines and are consistent with the assumption of abundant water vapor in their envelopes and with water being a major coolant of these circumstellar regions.